Numerical study of hydrodynamic flow of a Casson nanomaterial past an inclined sheet under porous medium

The main aim of the current paper is to investigate the mass and heat transportation of a Casson nanomaterial generated by the inclination of the surface. The magnetic field effect along with suction or injection are considered. The working nanomaterial is taken into consideration based on the concept of the Buongiorno nanofluid theory, which explores the thermal efficiencies of liquid flows under movement of Brownian and thermophoretic phenomena. The emergent system of differential expressions is converted to dimensionless form with the help of the appropriate transformations. This system is numerically executed by the implementation of Keller–Box and Newton's schemes. A good agreement of results can be found with the previous data in a limiting approach. The behavior of the physical quantities under concern, including energy exchange, Sherwood number, and wall shear stress are portrayed through graphs and in tabular form. The Nusselt number and Sherwood number are found to diminish against the altered magnitudes of Brownian motion and the inclination parameter. Moreover, the velocity profile decreases with the growth of the inclination effect. In the same vein, the buoyancy force and solutal buoyancy effects show a direct relation with the velocity field. The outcomes have promising technological uses in liquid‐based systems related to stretchable constituents.     

Performance analysis of hybrid/single nanofluids on augmentation of heat transport in lid-driven undulated cavity

This numerical study reveals the heat transfer performance of hybrid/single nanofluids inside a lid-driven sinusoidal trapezoidal-shaped enclosure. The right and left inclined surfaces of the trapezium have been considered as insulated, whereas the bottom sinusoidal wavy and the flat top surfaces of the enclosure as hot and cold, respectively. The governing partial differential equations of fluid's velocity and temperature have been resolved by applying the finite element method. The implications of Prandtl number (4.2-6.2), Richardson number (0.1-10.0), undulation number (0-3), nanoparticles volume fraction (0%-3%), and nanofluid/base fluid (water, water–copper (Cu), water–Cu–carbon nanotube, water–Cu–copper oxide (CuO), water–Cu–TiO₂, and water–Cu–Al₂O₃) on the velocity and temperature profiles have been studied. Simulated findings have been represented by means of streamlines, isothermal lines, and average Nusselt number of above-mentioned hybrid nanofluids for varying the governing parameters. The comparison of heat transfer rates using hybrid nanofluids and pure water has been also shown. The heat transfer rate is increased about 15% for varying Richardson number from 0.1 to 10.0. Blending of two nanoparticles suspension in base fluid has a higher heat transfer rate—approximately 5% than a mononanoparticle. Moreover, a higher average Nusselt number is obtained by 14.7% using the wavy surface than the flat surface of the enclosure. Thus, this study showed that applying hybrid nanofluid may be beneficial to obtain expected thermal performance.     

A Generalized Surface Chalcogenation Strategy for Boosting the Electrochemical N2 Fixation of Metal Nanocrystals

Electrocatalytic nitrogen reduction reaction (NRR) is a promising process relative to energy-intensive Haber–Bosch process. While conventional electrocatalysts underperform with sluggish paths, achieving dissociation of N₂ brings the key challenge for enhancing NRR. This study proposes an effective surface chalcogenation strategy to improve the NRR performance of pristine metal nanocrystals (NCs). Surprisingly, the NH₃ yield and Faraday efficiency (FE) (175.6 ± 23.6 mg h^–1 g^–1_Rh and 13.3 ± 0.4%) of Rh-Se NCs is significantly enhanced by 16 and 15 times, respectively. Detailed investigations show that the superior activity and high FE are attributed to the effect of surface chalcogenation, which not only can decrease the apparent activation energy, but also inhibit the occurrence of the hydrogen evolution reaction (HER) process. Theoretical calculations reveal that the strong interface strain effect within core@shell system induces a critical redox inversion, resulting in a rather low valence state of Rh and Se surface sites. Such strong correlation indicates an efficient electron-transfer minimizing NRR barrier. Significantly, the surface chalcogenation strategy is general, which can extend to create other NRR metal electrocatalysts with enhanced performance. This strategy open a new avenue for future NH₃ production for breakthrough in the bottleneck of NRR.     

Optimization of culture conditions for biohydrogen production from sago wastewater by Enterobacter aerogenes using Response Surface Methodology

Sago wastewater (SWW) causes pollution to the environment due to its high organic content. Annually, about 2.5 million tons of SWW is produced in Malaysia. In this study, the potential of SWW as a substrate for biohydrogen production by Enterobacter aerogenes (E. aerogenes) was evaluated. Response Surface Methodology (RSM) was employed to find the optimum conditions. From preliminary optimization, it was found that the most significant factors were yeast extract, temperature, and inoculum size. According to Face Centered Central Composite Design (FCCCD), the maximum hydrogen concentration and yield were 630.67 μmol/L and 7.42 mmol H₂/mol glucose, respectively, which is obtained from the sample supplemented with 4.8 g/L yeast extract concentration, 5% inoculum, and incubated at the temperature of 31 °C. Cumulative hydrogen production curve fitted by the modified Gompertz equation suggested that H_max, R_max, and λ from this study were 15.10 mL, 2.18 mL/h, and 9.84 h, respectively.     

The control of paracetamol particle size and surface morphology through crystallisation in a spray dryer

The parameters governing the crystallisation of paracetamol using various conventional techniques has been extensively studied, however the factors influencing the drug crystallisation using spray drying is not as well understood. The aim of this work was to investigate the crystallisation of an active pharmaceutical ingredient through evaporative crystallisation using a spray dryer to study the physicochemical properties of the drug and to use semi-empirical equations to gain insight into the morphology and particle size of the dried powder. Paracetamol solutions were spray dried at various inlet temperatures ranging from 60 °C to 120 °C and also from a series of inlet feed solvent compositions ranging from 50/50% v/v ethanol/water to 100% ethanol and solid-state characterisation was done. The size and morphology of the dried materials were altered with a change in spray drying parameters, with an increase in inlet temperature leading to an increase in particle Sauter mean diameter (from 3.0 to 4.4 µm) and a decrease in the particle size with an increase in ethanol concentration in the feed (from 4.6 to 4.4 µm) as a result of changes in particle density and atomised droplet size. The morphology of the dried particles consisted of agglomerates of individual crystallites bound together into larger semi-spherical agglomerates with a higher tendency for particles having crystalline ridges to form at higher ethanol concentrations of the feed.     

Unpatterned Bioactive Poly(Butylene 1,4-Cyclohexanedicarboxylate)-Based Film Fast Induced Neuronal-Like Differentiation of Human Bone Marrow-Mesenchymal Stem Cells

Herein, we present poly(butylene 1,4-cyclohexanedicarboxylate) (PBCE) films characterized by an unpatterned microstructure and a specific hydrophobicity, capable of boosting a drastic cytoskeleton architecture remodeling, culminating with the neuronal-like differentiation of human bone marrow-mesenchymal stem cells (hBM-MSCs). We have used two different filming procedures to prepare the films, solvent casting (PBCE) and compression-moulding (PBCE*). PBCE film had a rough and porous surface with spherulite-like aggregations (Ø = 10–20 μm) and was characterized by a water contact angle = 100°. PBCE* showed a smooth and continuous surface without voids and visible spherulite-like aggregations and was more hydrophobic (WCA = 110°). Both surface characteristics were modulated through the copolymerization of different amounts of ether-oxygen-containing co-units into PBCE chemical structure. We showed that only the surface characteristics of PBCE-solvent-casted films steered hBM-MSCs toward a neuronal-like differentiation. hBM-MSCs lost their canonical mesenchymal morphology, acquired a neuronal polarized shape with a long cell protrusion (≥150 μm), expressed neuron-specific class III β-tubulin and microtubule-associated protein 2 neuronal markers, while nestin, a marker of uncommitted stem cells, was drastically silenced. These events were observed as early as 2-days after cell seeding. Of note, the phenomenon was totally absent on PBCE* film, as hBM-MSCs maintained the mesenchymal shape and behavior and did not express neuronal/glial markers.     

12CrNi3钢外锁止套局部表面激光淬火工艺

利用半导体激光宽带对12CrNi3外锁止套局部进行表面淬火处理,并对处理后的零件进行外观检验、显微组织观察、硬度检测分析和摩擦磨损试验。试验结果表明:采取定光斑方式,激光头到工件表面扫描区域中心点距离375 mm(离焦量为0),工件倾斜22°,激光头倾斜18°,温度1350 ℃,扫描速度9 mm/s,单道扫描后表面平整性最好。表面激光淬火硬化层为750～1000 μm,最浅处为443.1 μm,硬化区组织为极细小马氏体组织,硬度达600～700 HV0.2,是基体硬度的2倍左右, 约为渗碳+淬火态硬度的1.3倍,且相变硬化区耐磨性能明显提高。     

二层沟槽织构对机床导轨表面润滑特性的影响

通过构建二层沟槽织构模型，仿真研究沟槽织构表面的流体动力效应。结果表明：沟槽容积相同时，与单层沟槽相比，二层沟槽的平均油膜压力可以达到单层沟槽的2.31倍；保持二层沟槽的量纲一总深度[β]1、第一层沟槽量纲一宽度[α]1不变时，随着第二层量纲一深度[β]2的增大，平均油膜压力先增大后减小，[β]2为4.4时，平均油膜压力达到最大值；第二层沟槽的量纲一宽度[α]2从0.25增大到0.45时，沟槽内的旋涡区也随之增大，平均油膜压力逐渐减小。